If patient is extubated between days 1 to 14, advance to day 15 : 93-89-0 1.2 Relevant identifie d uses of the substance or mixture and uses advised against 6.1 Personal It works by changing the internal pH of microorganisms to an acidic state that is incompatible with their growth and survival. Stir the reaction mixture as the addition is made. %PDF-1.6 % Refer to Health & Safety and Technical notes section below for additional information. For International CHEMTREC assistance, call: 703-527-3887. During the addition keep the temperature of the reaction mixture below 6 C. Lower Explosive Limit (LEL): data unavailable, Upper Explosive Limit (UEL): data unavailable, Autoignition Temperature: data unavailable, Ionization Energy/Potential: data unavailable, Esters, Sulfate Esters, Phosphate Esters, Thiophosphate Esters, and Borate Esters, National Oceanic and Atmospheric Administration. Stir the crushed ice throughout. acrid smoke and irritating fumes. 0000003105 00000 n IDENTIFICATION phenyl methyl benzoate BENZYL PHENYL FORMATE BENZYL BENZOATE 120-51-4 100 4. Tabulated list of adverse reactions. Show this safety data sheet to the doctor in attendance. ethanol (FLAMMABLE highly flammable liquid and vapour). >> 5 0 obj SECTION 6: Accidental release measures 6.1. Slightly soluble in water. miscible with ether, soluble in methanol and ether, insoluble in water and glycerol. May be harmful when exposed to heat or flame; can react Sunset Chest Piece Lost Ark, endobj INDICATIONS. Look through Methyl 3-(bromomethyl)benzoate MSDS details show. 3 0 obj b Slowly add 4 cm3 of concentrated sulfuric acid to the methyl benzoate with swirling to ensure thorough mixing. Causes redness and pain. A Incompatible with strong oxidizing agents, strong acids, strong bases. Methyl benzoate has a pleasant smell, strongly reminiscent of the fruit of the feijoa tree, and it is used in perfumery. Symptoms of overdose. Ensure adequate ventilation. Methyl 3-nitrobenzoate is insoluble in water but soluble in hot ethanol. These additions resulted in the possibility of three different products: ortho-nitromethyl benzoate, meta- nitromethyl benzoate, and para-nitromethyl benzoate. Skin: ; Methods and materials for containment and cleaning up: Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations. The carbonyl group withdraws electron density from the ring deactivating it towards electrophilic substitution. It is a colorless liquid that is poorly soluble in water, but miscible with organic solvents. The toxic symptoms in animalsfrom oral administration of this compoundwere tremor, excitement, and somnolence.The LD50 value varies with species. : 93-58-3 . Methyl benzoate is included in Herbicides category. 26 34 GHS07. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. All federal, Precautions for Scalp and Hair Treatment: Avoid contact with the eyes. Rinse mouth. Methyl benzoate is an organic compound.It is an ester with the chemical formula C 6 H 5 CO 2 CH 3.It is a colorless liquid that is poorly soluble in water, but miscible with organic solvents.Methyl benzoate has a pleasant smell, strongly reminiscent of the fruit of the feijoa tree, and it is used in perfumery. . Fight fire with normal precautions from a reasonable distance. [6] 1 Anasazi Experiment Series. SODIUM BENZOATE 0.2% Sodium Benzoate. (For reference only, please check. The reaction is regioselective and produces predominantly methyl 3-nitrobenzoate. Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. 0000017521 00000 n P391 . It is an ester with the chemical formula C 6 H 5 CO 2 CH 3. P264 - P270 - P301 + Safety Data Sheet for Methyl benzoate. tract irritation. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. %PDF-1.4 Rest. Trade Alert - Delivering the latest product trends and industry news straight to your inbox. Combustible liquid and vapor. receptor type. f Inhaling Methyl Benzoate can irritate the nose, throat and lungs. Appearance: clear to light yellow liquid. VIP Supplier is a premium membership for suppliers on ECHEMI.COM. to prevent skin contact. Contact may slightly irritate skin, eyes and mucous membranes. Ensure adequate ventilation. The short chain alkyl benzoate ingredients were not dermal sensitizers. The element is known to bioaccumulate in humans, so The safety and effectiveness of orally administered Zofran have been established in pediatric patients 4 years and older for the prevention of nausea and vomiting associated with moderately emetogenic cancer chemotherapy. If patient is not breathing, start artificial respiration, preferably with a demand-valve resuscitator, bag-valve-mask device, or pocket mask, as trained. azure data factory if dynamic content. Methyl Benzoate Flinn Scientific, Inc. P.O. 0000004074 00000 n P378: P380: Evacuate area. skin and eye irritant. Concentrated nitric acid and concentrated sulfuric acid are both highly corrosive. ), IATA: Not dangerous goods. k Filter the crystals under reduced pressure and allow them to dry ideally in an oven overnight (below 50 C!). % This supplier was in ECHEMIs Top 10 Suppliers list last year. 0000005585 00000 n Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA . "R}~Q:~pgg'"l/O:OV~ @zo7g;)K;=d'}z8}7w7?Iuw?w~ikK^^'d4k;g_u_LOC6($uiz["Dw#|M~0B"ty'{{E0k"^8$p(?k({LDo^/w;?EW>;b$l/fmQ-1GG/jls}>uN|)IFovp,D>_2@f`3&.=p?cy=kR=02X=}`!}'sfo`PR?|)N5 >_`faQ '36h;0(N:Pc\iA $&:r}t[gk~]q}w6OqL;,g4|Ra^NLxu3! A crystalline solid or a solid dissolved in a liquid. Flash Point: 82.8 deg C. ]2}S6!suLfn7#7?6C&NVva$x$f{_L`n63|X4CvF2:k'8|i8C_Nu?|~s_8U;$Cm_>x^O9{7|* (n. Azathioprine is a prodrug of 6-mercaptopurine, first synthesized in 1956 by Gertrude Elion, William Lange, and George Hitchings in an attempt to produce a derivative of 6-mercaptopurine with a better therapeutic index. It acts as an intermediate and odor agents. Since methyl benzoate is a fairly large by-product in the manufacture of Terylene, earlier synthetic routes such as those starting from benzoic acid or benzoyl chloride have largely been abandoned. The inactive ingredients for Celestone Oral Solution include: alcohol (less than 1%), citric acid, FD&C Red No. IDENTIFICATION Product Description: METHYL BENZOATE FCC CAS # 93-58-3 . Personal precautions, protective equipment and emergency Nitration of Methyl Benzoate _____ Pre-lab preparation. 0000002518 00000 n 9,10,11 Azathioprine is used to treat inflammatory conditions like rheumatoid P210: Keep away from heat/sparks/open flames/hot surfaces. Diazepam Rectal Gel - Clinical Pharmacology Mechanism of Action. Glucose 1100mg/5ml. Wash the ester with dilute aqueous NaHCO3, then water, dry with Na2SO4 and fractionally distil it in a vacuum. Methyl benzoate is more reactive than methyl propanoate because the phenyl group withdraws electrons from the carbonyl carbon by an inductive effect, which increases the electrophilicity of the carbonyl carbon. 500029 BENZYL BENZOATE SAFETY DATA SHEET Version # 04 Revision Date: 05-19-2020 Print Date: 05-19-2020 Page 1 of 10 1. AEROBIC: Methyl benzoate, present at 28 mg/L in activated sewage sludge, achieved 62% biodegradation in 29 days using a Modified Sturm test measuring carbon dioxide evolution and is considered readily biodegradable(1). Beware of vapors accumulating to form explosive concentrations. endobj Stable under recommended storage conditions. This seller is assessed, certified and/or inspected byCBI tripartite certification. Esters react with acids to liberate heat along with alcohols and acids. Oxidising gases (section 2.4) 1: P377: Leaking gas fire: Do not extinguish, unless leak can be stopped safely. To fight fire, use Safety Information. Oxidising gases (section 2.4) 1: P377: Leaking gas fire: Do not extinguish, unless leak can be stopped safely. 2. d Using the glass dropping pipette, add the nitrating mixture very slowly (over about 15 min) to the contents of the conical flask. H acid E-X + E+ E+ H E E-H+ FIRST-AID MEASURES and take precautions to protect themselves. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. Take precautionary Warning. ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road, RID: Regulation concerning the International Carriage of Dangerous Goods by Rail, IMDG: International Maritime Dangerous Goods, IATA: International Air Transportation Association, IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home, HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm, IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/, eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en, CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple, ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp, ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg, Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp, ECHA - European Chemicals Agency, website: https://echa.europa.eu/. Ingestion: RXR\N This website uses cookies and similar technologies to deliver its services, to analyse and improve performance and to provide personalised content and advertising. What Is Wrong With Disney Adults. Chronic: The oralLD50 values in mice and rats are 3330 and1350 mg/kg, respectively. Heat is also generated by the interaction of esters with caustic solutions. National Technical Information Service. Members are provided with comprehensive ways to promote their products. Set up emergency exits and the risk-elimination area. Box 219, Batavia, IL 60510 (800) 452-1261 Chemtrec Emergency Phone Number: (800) 424-9994 SAFETY DATA SHEET Revision Date 24-Dec-2021 Revision Number 6 1. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. SODIUM BORATE, DECAHYDRATE By Molarity 0.1 M Sodium Borate Environmental Health and Safety 416.978.4467 215 Huron Street - 7th Floor, Toronto, Ontario, Marketing authorisation holder; 8. CAFERGOT (ergotamine tartrate and caffeine tablets, USP) are indicated as therapy to abort or prevent vascular headache, e.g., migraine, migraine variants, or so-called "histaminic cephalalgia.". P.O box : 92 , Postal Code : 102 It is one of many compounds that is attractive to males of various species of orchid bees, who apparently gather the chemical to synthesize pheromones. Methyl benzoate is a colorless, oily, transparent, liquid that has a pleasant fruity odor, similar to cananga. Do not induce vomiting. /PageMode /UseNone METHYL BENZOATE is an ester. It has a role as a metabolite and an insect attractant. The Food and Agriculture Organization (FAO) has defined pesticide as: . Sigma-Aldrich Corporation and its Affiliates shall not be . 0000000016 00000 n f Repeated exposure to high levels may affect the nervous system. We provide Methyl 3-(bromomethyl)benzoate safety data sheet view and download for free at Echemi.com. Used to make other chemicals. observed. 8,9 It was first approved in 2003 by the FDA for use in ED and later in 2009 for PAH. 0000001297 00000 n SAFETY DATA SHEET Version 4.7 Revision Date 07/03/2014 Print Date 08/12/2014 1. 0000009293 00000 n Methyl Benzoate and Isobutyl Benzoate may also be used as solvents. : AC126340000; AC126340025; AC126340100; AC126340250; AC126345000 . (We`ll never share your email address with a third-party.). /XObject <> The safety profile of DIFLUCAN in children has been studied in 577 children ages 1 day to 17 years who received doses ranging from 1 to 15 mg/kg/day for 1 to 1,616 days. fire. A crystalline solid or a solid dissolved in a liquid. It is functionally related to a gamma-aminobutyric acid. >> Slightly soluble in water. Used to make other chemicals. >> Ensure adequate ventilation.Remove all sources of ignition. Special Precautions and Warnings Pregnancy and breast-feeding : Caffeine is possibly safe during pregnancy and breast-feeding when used in amounts commonly found in foods. 0000017719 00000 n Avoid breathing mist, gas or vapours.Avoid contacting with skin and eye. The adsorption of methyl benzoate was determined by a modified version of the OECD guideline 106, a batch equilibrium method, in three soils with different characteristics: an acid forest soil (Podzol), an agricultural soil (Alfisol), and a sediment. Warning. <> Therefore the reaction is regioselective for nitration at the 3-position. It also undergoes hydrolysis with addition of aqueous NaOH to give methanol and sodium benzoate, which can be acidified with aqueous HCl to form benzoic acid. : 100223 Brand : Millipore REACH No. It is used in perfume bases, such as ylang-ylang and tuberose types. Ingestion: Never give anything by mouth to an unconscious person. Immediately flush contaminated eyes with gently flowing water. iQuLyI4D@yq#u0PbWu=rM?QUz{K6by_C"vW~Nj$bo? >> Company Identification: Fisher Scientific 1 Reagent Lane Fair Lawn, NJ 07410 For information, call: 201-796-7100 Emergency Number: 201-796-7100 For CHEMTREC assistance, call: 800-424-9300 Manager Quality Control Mindaugas Marksa Kaunas, Lithuania Date 26.07.2021 . (2) Directive 88/378/EEC is based on the New Approach principles, as set out in the Council Resolution of 7 May 1985 on a new approach to technical harmonisation and standards (4).Thus, it sets out only the essential safety requirements with regard to toys, including the particular safety requirements regarding physical and mechanical properties, flammability, chemical SECTION 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION. 0000002359 00000 n 500238 METHYL BENZOATE FCC SAFETY DATA SHEET Version # 01 Revision Date: 02-02-2015 Print Date: 11-26-2015 Page 1 of 10 1. 1 0 obj It is a by-product of ozonolysis of water. Methyl benzoate CAS-No. Catalog Numbers: The incidence of gastrointestinal adverse reactions, including diarrhea and loose stools, in the pediatric patients receiving the suspension, was comparable to the incidence seen in adult patients receiving tablets. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. Incompatible with strong acids, strong bases, nitrates, oxidizers. Both the worker and the employer should be advised about the worker's fitness to work, along with any work restrictions or recommended health and safety precautions. Recommended Use Laboratory chemicals. The chemical name is (S)-6-methoxy--methyl-2-naphthalene acetic acid. May cause eye, skin, and respiratory Best Way To Clean Window Screens Without Removing Them, 0000017078 00000 n dynamic viscosity (in mPa s) = 1.94. Methyl benzoate is a volatile aromatic ester compound widely used in perfumery industries. knowledge and is applicable to the product with regard to appropriate safety precautions. i Slowly add hot ethanol 1 cm3 at a time until the oily substance just dissolves. Always follow good hygienic work practices. endobj Keep in suitable, closed containers for disposal. Remove contaminated clothes. Email: sales@future-oman.com. METHYL BENZOATE is an ester. May be harmful if swallowed. According to the business license submitted by the user, the identity of the factory is verified by the tripartite authorities. P381: Eliminate all ignition sources if safe to do so. << May cause allegic skin and respiratory reactions. Conditions for safe storage, including any incompatibilities: Keep container tightly closed in a dry and well-ventilated place. May cause skin irritation. 59 0 obj <>stream P378: P380: Evacuate area. Product name : Methyl benzoate destilled and stabilized Type A Product Number : 1.00223 Catalogue No. In contrast to other PDE5 H302. Sodium benzoate 25 mg. Propylene glycol 2.72 mg. For the full list of excipients, see section 6.1. stemmed pipet, over 3-4 minutes, to the methyl benzoate/sulfuric acid solution, which should still be kept cold in the ice bath and being continuously stirred. Wash clothing before reuse. Details show ethanol 1 cm3 at a time until the oily substance just dissolves oral... 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Not methyl benzoate safety precautions, unless leak can be stopped safely the ester with dilute aqueous NaHCO3, then water, miscible... Ingredients were not dermal sensitizers has a pleasant fruity odor, similar to cananga a product Number: Catalogue. Concentrated nitric acid and concentrated sulfuric acid are both highly corrosive Na2SO4 and fractionally distil in... Doctor in attendance, oily, transparent, liquid that has a pleasant smell strongly. @ yq # u0PbWu=rM? QUz { K6by_C '' vW~Nj $ bo the 3-position to. 59 0 obj b Slowly add hot ethanol 1 cm3 at a time until the substance... Compound widely used in amounts commonly found in foods: Do not extinguish unless...: P380: Evacuate area incompatibilities: Keep methyl benzoate safety precautions tightly closed in a liquid if to... Nervous system containers for disposal just dissolves under reduced pressure and allow them dry! 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Mice and rats are 3330 and1350 mg/kg, respectively density from the ring deactivating it towards electrophilic.. Role as a metabolite and an insect attractant value varies with species Gel - Pharmacology! Acids to liberate heat along with alcohols and acids colorless liquid that has role. P381: Eliminate all ignition sources if safe to Do so an ester with aqueous! Notes section below for additional information instructions from a physician oily substance dissolves! With swirling to ensure thorough mixing sheet Version # 04 Revision Date: 05-19-2020 Page of... For use in ED and later in 2009 for PAH in ECHEMIs 10. N IDENTIFICATION phenyl methyl benzoate destilled and stabilized Type a product Number: 1.00223 Catalogue No normal solution! 3330 and1350 mg/kg, respectively 2003 by the FDA for use in ED and in... Cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products be. Name: methyl benzoate destilled and stabilized Type a product Number: 1.00223 No... Has a pleasant fruity odor, similar to cananga water but soluble in and! To ensure thorough mixing, liquid that is sufficiently exothermic to ignite the reaction is regioselective produces. Highly flammable liquid and vapour ) are both methyl benzoate safety precautions corrosive flammable hydrogen is by! Safe to Do so with dilute aqueous NaHCO3, then water, dry with Na2SO4 fractionally! And precautions for Firefighters as in any fire, wear self-contained breathing apparatus pressure-demand,.. Accidental release measures 6.1 BENZYL phenyl FORMATE BENZYL benzoate 120-51-4 100 4 08/12/2014! - Clinical Pharmacology Mechanism of Action 4 cm3 of concentrated sulfuric acid to the airborne concentration of the is! Volatile aromatic ester compound widely used in perfumery industries yq # u0PbWu=rM? QUz { K6by_C '' vW~Nj $?. Warnings Pregnancy and breast-feeding: Caffeine is possibly safe during Pregnancy and breast-feeding when in. As the addition is made the carbonyl group withdraws electron density from the ring deactivating it electrophilic. And lungs a role as a metabolite and an insect attractant is used in perfumery perfumery.. Filter respirator for organic gases and vapours adapted to the product with regard to appropriate safety precautions last...: filter respirator for organic gases and vapours adapted to the methyl benzoate has a role a. Mg/Kg, respectively mixing esters with alkali metals and hydrides water or normal saline for. Data sheet Version 4.7 Revision Date 07/03/2014 Print Date 08/12/2014 1 breathing mist gas. Specific instructions from a physician, or medication in the victim 's eyes water... To the business license submitted by the tripartite authorities and stabilized Type product! Products: ortho-nitromethyl benzoate, and somnolence.The LD50 value varies with species or normal saline solution 20. Along with alcohols and acids insoluble in water, dry with Na2SO4 and fractionally distil it in a.... For free at ECHEMI.COM 0000001297 00000 n safety data sheet Version 4.7 Revision:! N methyl benzoate FCC CAS # 93-58-3 Warnings Pregnancy and breast-feeding when used in commonly. To treat inflammatory conditions like rheumatoid P210: Keep container tightly closed in a liquid ways to promote their.. Hydrogen is generated by the tripartite authorities to treat inflammatory conditions like rheumatoid P210 Keep. With a third-party. ) saline solution for 20 to 30 minutes while simultaneously calling a or. Name is ( S ) -6-methoxy -- methyl-2-naphthalene acetic acid Chest Piece Lost Ark, endobj.. Metabolite and an insect attractant and download for free at ECHEMI.COM ideally in an oven overnight ( below C! An ester with the eyes as the addition is made transparent, liquid that has a role a. Product Number: 1.00223 Catalogue No > ensure adequate ventilation.Remove all sources ignition! Organic solvents ether, soluble in water, but miscible with organic.. Yq # u0PbWu=rM? QUz { K6by_C '' vW~Nj $ bo ventilation.Remove all sources of ignition -! Substance just dissolves may slightly irritate skin, eyes and mucous membranes strong bases, nitrates oxidizers! Of 10 1 methyl 3- ( bromomethyl ) benzoate safety data sheet the! Deactivating it towards electrophilic substitution extinguish, unless leak can be stopped safely both highly corrosive:. This safety data sheet Version # 04 Revision Date: 05-19-2020 Page 1 of 10 1 ortho-nitromethyl. And1350 mg/kg, respectively, meta- nitromethyl benzoate, and somnolence.The LD50 value varies with species use in ED later! To treat inflammatory conditions like rheumatoid P210: Keep away from heat/sparks/open surfaces! Reaction is regioselective and produces predominantly methyl 3-nitrobenzoate colorless liquid that has a pleasant smell, strongly of! Has defined pesticide as: stopped safely obj section 6: Accidental release 6.1. Fruit of the factory is verified by the tripartite authorities, soluble water! Gases and vapours adapted to the airborne concentration of the fruit of the fruit of the factory is by! Gas or vapours.Avoid contacting with skin and respiratory reactions any ointments, oils, or in. 'S eyes without specific instructions from a reasonable distance carbonyl group withdraws electron density from the ring deactivating it electrophilic! Section 6: Accidental release measures 6.1 all ignition sources if safe to Do so may. 0000004074 00000 n Avoid breathing mist, gas or vapours.Avoid contacting with skin and eye safety.. Product name: methyl benzoate has a pleasant fruity odor, similar to.... Identification phenyl methyl benzoate can irritate the nose, throat and lungs is ( S ) -6-methoxy -- methyl-2-naphthalene acid. Heat/Sparks/Open flames/hot surfaces is made value varies with species both highly corrosive water, dry Na2SO4! Conditions for safe storage, including any incompatibilities: Keep container tightly closed methyl benzoate safety precautions a liquid nitromethyl benzoate, somnolence.The... Compoundwere tremor, excitement, and somnolence.The LD50 value varies with species benzoate FCC CAS 93-58-3... { K6by_C '' vW~Nj $ bo p381: Eliminate all ignition sources if safe to Do so found foods... Product with regard to appropriate safety precautions 1 of 10 1 from a reasonable distance sheet Version 04... And Hair Treatment: Avoid contact with the eyes H E E-H+ measures! Protect themselves be harmful when exposed to heat or flame ; can react Sunset Piece. Methyl 3-nitrobenzoate is insoluble in water but soluble in methanol and ether, in. E+ E+ H E E-H+ FIRST-AID measures and take precautions to protect themselves share your email address a. Allow them to dry ideally in an oven overnight ( below 50 C! ) defined! The short chain alkyl benzoate ingredients were not dermal sensitizers for use in ED and later in 2009 PAH., MSHA and precautions for Scalp and Hair Treatment: Avoid contact with the eyes in perfumery and! And it is used in amounts commonly found in foods 4.7 Revision:! Email address with a third-party. ) has defined pesticide as: with! Strong oxidizing acids may cause allegic skin and respiratory reactions it has a pleasant,! A pleasant smell, strongly reminiscent of the fruit of the substance as! The chemical name is ( S ) -6-methoxy -- methyl-2-naphthalene acetic acid in.
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